Chemistry

Empirical Formula

Determine the simplest whole-number ratio of atoms in a compound.

Mole Ratio = Mass Percentage / Atomic Mass; then simplify to the smallest whole-number ratio

Formula Explanation

Convert element masses to mole amounts, divide by the smallest amount, and obtain a whole-number ratio.

Variables Explained

Mass percentage = Element proportion by mass; Atomic mass = Relative atomic mass.

Solved Example

A compound has a 1:2 mole ratio of carbon to oxygen. Give its empirical formula.
The empirical formula is CO₂.

Exam Tip

Multiply all ratios by the same integer if needed to obtain whole numbers.